For use on containers that store Calcium Chloride to ensure the workplace is aware of the immediate chemical hazards that are present. The external phase is oil and does not allow the water to contact the formation. <<
Calcium Chloride Alkali Chlorides Moisture 93% <5% <4% Synonyms/ : Anhydrous Calcium Chloride, Prilled Calcium Chloride, Calcium Dichloride Common Names 4. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. If you are allergic to calcium chloride; any part of calcium chloride; or any other drugs, foods, or substances. �@h�A��� h���"Fh���c���91�@( If victim is conscious and alert, give 2-4 cupfuls of water. Calcium chloride is a non-inflammable substance. �nVf.�i��N��ΆP�` @hN ��r� ������
����� The Romans used blood, pig's fat and milk as additions to pozzolanic cements to improve their workability and durability. According to the OSHA Hazard Communication Standard Final Rule a label must be on the immediate container of every hazardous chemical. The label is an immediate type of warning since it is present in the work area, right on the actual container of a hazardous chemical. 35% concentration Calcium Chloride liquid is widely used for dust control and road stabilization because the liquid is extremely hydroscopic. Dependable 3M adhesive vinyl that is built to resist harsh conditions. Chronic (long-term) exposure to chlorine gas in workers has resulted in respiratory effects, including eye and throat irritation and airflow obstruction. Calcium chloride is used in concrete mixes to accelerate the initial setting, but chloride ions lead to corrosion of steel rebar, so it should not be used in reinforced concrete. Relevant identified uses of the substance or mixture and uses advised against 1.3. 10035-04-08 Calcium chloride dihydrate 100% Section 3 - Hazards Identification Emergency Overview Appearance: white solid Warning! This data was compiled from the Hazardous Materials Table from the United States "Code of Federal Regulations" title 49 section 172.101. Calcium chloride is hygroscopic. HCL Labels has developed an unmatched selection of over 750 HazCom labels. 7,CALCIUM CHLORIDE 95/98%,CALC CHLORIDE 77-80% ROAD GRADE REACH registration number 01‐2119494219‐28 CAS number 10043-52-4 EU index number 017-013-00-2 EC number 233-140-8 1.2. >>
Calcium chloride is an economical, dependable additive for obtaining optimum moisture during construction. Acetyl Chloride 3 3 2 W Acetylene 1 4 3 Acetyl Peroxide 1 2 4 Acrolein 3 3 2 Acrolein Dimer 1 2 1 ... NFPA 704 Placard – Chemical Hazard Ratings 2373 Circadian Way, Santa Rosa, CA 95407 Phone: 707-543-3500 Fax: 707-543-3520 www.SantaRosaFD.com ... Calcium Chlorate 2 0 2 OX Calcium Cyanide 3 0 0 Bromine trifluoride rapidly attacks calcium chloride [Mellor 2 Supp. Chlorine is a potent irritant to the eyes, the upper respiratory tract, and lungs.
Compliant with the OSHA Hazard Communication Standard 1910.1200 and aligned with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS), Operating range of -65F (-54C) to 225F (107C). Further notes are below. View information & documentation regarding Calcium chloride, including CAS, MSDS & more. CALCIUM CHLORIDE (ALL GRADES) SDS no. 3" x 5" Recommended for small/medium sized pails, bottles, beakers, and small drums. Originally published 1974. !�n� <<
3" x 5" Recommended for small/medium sized pails, bottles, beakers, and small drums. May react vigorously with oxidizing materials. If you have any of these health problems: Breathing problems, high calcium levels, or low calcium … Keep container closed. ��re@P�E�{���(�َ���t�֕2� Va�bT�=��Y It is capable of absorbing moisture from the air. Recommended Uses. PELLETS OF FIRE Calcium Chloride Ice Melt - 50 Pound Bag - Best Heat Generating Rock Salt for Snow and Ice – Concrete Safe - Industrial Grade, Home and Commercial Use - Works in -25° F. 4.4 out of 5 stars 291. 1:164, 165 1956]. @jɐ����`�̑B��wq���x�����l/,[�c#*�%�� � Ĵˎ�����<
Corrosion-Inhibited Calcium Chloride: Liquid Calcium Chloride is hard on ice, but easy on corrosion. ), Oxidizer Cabinet Sign - 3.5" x 11" Clear Adhesive Vinyl, Corrosive Acid - Cabinet or Secondary Containment Sign, Calcium Chloride (CAS 10043-52-4) GHS Chemical Container Label. Reference Sources. Free 2nd Day UPS for order of $100 or more. The powdered mixture of the acetylide and iron oxide and iron chloride burns violently upon ignition, producing molten iron. The addition of small amounts of certain materials to concrete to promote desirable properties is as old as the use of cement itself. Calcium chloride 10043-52-4 60-100 % 3. Tested to withstand exposure to Acetone, Dichloromethane, Hydrofluoric Acid, and other tough chemicals and solvents. Avoid contact with eyes, skin and clothing. %PDF-1.2
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Calcium chloride must be administered slowly through the vein. ��" The growing need for corrosion-inhibited deicers has prompted manufacturers to explore their production. Details of the supplier of the safety data sheet Durable laminate that increases the label strength and resistance. endobj
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Aluminum chloride is commonly used topical antiperspirant. 5, 862]. 4.4 Special warnings and precautions for use. My Account; Customer Service; Free Shipping for order of $29.95 and more. 7647-14-5 5 - 26 Not classified Full text of H-phrases: see Section 16. In addition, at no cost, HCL can quickly produce a fully compliant OSHA HazCom label for any product requiring secondary container labeling. The anhydrous form of calcium chloride may also be used for this purpose and can provide a measure of the moisture in concrete. 68-03-2214 Project Officer Ira WiIder Oil and Hazardous … First aid measures 4.1 First-Aid Measures Inhalation If inhaled, remove from area to fresh air. Regulatory Information S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 10035-04-8 Calcium chloride No No No 7732-18-5 Water No No No 3. endstream
CALCIUM CARBIDE is a reducing agent. 4" x 7" Recommended for medium pails, bottles, beakers, drums, and tubs. ��S�[u�����&(m)��I&�N���e��>�&�Hu*��4���C-/�6�J��U�&�
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For skin exposure, consult with a burn specialist or plastic surgeon. �p{-��P�0U�v��@�*���TF�2�*;pg�x��^�Zs0���#p��� �з�B��PQH�pƈ 2 Calcium Chloride uses are many. ), Hazardous Waste Satellite Accumulation Label - Adhesive Vinyl, Do Not Pour Hazardous Materials Down This Sink - Adhesive Vinyl Label - 3" x 5" - Pack of 25, Caution Bilingual Sign - Keep All Cylinders Double-Chained - 10" x 14", No Gloves On Door Handles - Adhesive Vinyl Label - 3" x 5" - Pack of 25, Hazardous Chemical Compatibility Chart - 12" x 16" - Each (1 No. Calcium chloride is an odorless, white, crystalline solid compound that is highly soluble in water. Injection of 5% calcium gluconate is indicated as the primary medical treatment for large burns. However, when it comes in contact with metals like zinc or sodium, it produces hydrogen, which is highly inflammable. 6.1a Toxic substances which are liable to cause death or serious injury to human health if inhaled, swallowed or by skin absorption (potassium cyanide, mercuric chloride).6.1b (Now PGIII) Toxic substances which are harmful to human health (N.B this symbol is no longer authorized by the United Nations) (pesticides, methylene chloride). A type of salt, this chemical is hygroscopic, which means it can attract and absorb water molecules from its surroundings. Full depth reclamation When recycling roads through full depth reclamation, calcium chloride can provide a stabilized base that can withstand traffic even before the wearing … In addition, it doesn't raise the soil's pH, so calcium can be delivered to plants without altering the soil's chemistry. For this reason, we should ensure that calcium chloride is kept away from these metals. Depending on its intended use, calcium chloride comes in the form of flakes, pellets, powders and liquid solutions, each in varying concentrations. endobj
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May cause severe respiratory and digestive tract irritation with possible burns. 98. 4" x 7" Recommended for medium pails, bottles, beakers, drums, and tubs. FREE Shipping by Amazon. Please see our information page here. The water phase of oil-based mud can be freshwater, or a solution of sodium or calcium chloride. Header Search (800) 952-1457 Mon - Fri 8:00am to 7:00pm EST; Shopping Cart 0 … 1. Tested to withstand exposure to Acetone, Dichloromethane, … 4 0 obj
Get medical attention if respiratory irritation develops or if breathing becomes difficult. 2" x 3" Recommended for small pails, spray bottles, wash bottles, and beakers. Calcium chloride can be bought in the form of flakes containing 77–80% of calcium chloride or granules containing 94% of calcium chloride. /Filter /LZWDecode
Transport carriers are required to display hazardous materials placards when transporting dangerous goods. This product is a/an white powder. ��c��XW��$�xj���Oo�U#��BU�@����f��S��"��� K���3p�IVP�8Ea.sQ� Ref. 9 0 obj
----- EPA-600/2-77-227 November 1977 MANUAL FOR THE CONTROL OF HAZARDOUS MATERIAL SPILLS VOLUME ONE SPILL ASSESSMENT AND WATER TREATMENT TECHNIQUES by K. R. Huibregtse, R. C. Scholz, R. E. Wullschleger J. H. Moser, E. R. Bellinger, and C. A. Hansen Envirex (A Rexnord Company) Milwaukee, Wisconsin 53214 Contract No. �@h�A��� h���"Fh���c���91�@( Calcium Chloride (CAS 10043-52-4) GHS Chemical Container Label; Dependable 3M adhesive vinyl that is built to resist harsh conditions. Chlorine is a commonly used household cleaner and disinfectant. Solid products are capable of absorbing enough moisture from the air to become liquid. We should also avoid storage of calcium chloride in containers made of any of these substances. 2715
Call or Email, GH1-2943-VN-0023,GH2-2943-VN-0023,GH3-2943-VN-0023,GH4-2943-VN-0023,GH1-2943-VN-0023-5,GH2-2943-VN-0023-5,GH3-2943-VN-0023-5,GH4-2943-VN-0023-5,GH1-2943-VN-0035,GH2-2943-VN-0035,GH3-2943-VN-0035,GH4-2943-VN-0035,GH1-2943-VN-0035-5,GH2-2943-VN-0035-5,GH3-2943-VN-0035-5,GH4-2943-VN-0035-5,GH1-2943-VN-0047,GH2-2943-VN-0047,GH3-2943-VN-0047,GH4-2943-VN-0047,GH1-2943-VN-0047-5,GH2-2943-VN-0047-5,GH3-2943-VN-0047-5,GH4-2943-VN-0047-5,GH1-2943-VN-0812,GH2-2943-VN-0812,GH3-2943-VN-0812,GH4-2943-VN-0812, GH12943VN0023,GH22943VN0023,GH32943VN0023,GH42943VN0023,GH12943VN00235,GH22943VN00235,GH32943VN00235,GH42943VN00235,GH12943VN0035,GH22943VN0035,GH32943VN0035,GH42943VN0035,GH12943VN00355,GH22943VN00355,GH32943VN00355,GH42943VN00355,GH12943VN0047,GH22943VN0047,GH32943VN0047,GH42943VN0047,GH12943VN00475,GH22943VN00475,GH32943VN00475,GH42943VN00475,GH12943VN0812,GH22943VN0812,GH32943VN0812,GH42943VN0812, ANSI Hazard Identification Signs And Labels, Biohazard/Infectious Waste Signs And Labels, Housekeeping/Company Policy Signs And Labels, Machine And Equipment Safety Signs And Labels, SDS (Safety Data Sheet) Projecting Sign - 8" x 12" 3D, Warning - May Form Explosive Peroxide - 1.5" x 2.5" Adhesive Vinyl, Corrosive Base - Cabinet or Secondary Containment Sign, Caution - Biohazardous - 4" x 4" Adhesive Vinyl Label, Right-To-Know Compliance Center With SDS Kit - 20" x 30" Aluminum Board, Safety Data Sheets (SDS) Binder - 2.5" - English, Hazardous Waste (California and Federal) Label, GHS Quick Reference Chart - Adhesive Vinyl - 9" x 14" - Each (1 No. bF�i���h�@J�O�Q��\@R#�ÉP�4���sM��D��N9��q�8f4�QHp�i���э�]0��i�Rh-��Eӡ�ֱk�[FY4��3�D���RB-�$�$�M̒ ��$�E��2�qu��3��Az|1�H��=h�k!�c��A� �w&�J�].l@S ��ő�A��mLd.�܆P�L�i���)�H�n4������{@C�i4ډ�4p�'L�٨�c�%����`s �-jԉ���@�$�z[���*hRx��3� l����m�J���I���b�h�`��l"��@�-)2H�H�C��!�60IB"��K� Rapid injection may cause tingling sensations, calcium taste, sense of oppression and "heat wave". May cause severe eye and skin irritation with possible burns. On lawns and farms, it provides an immediate source of calcium with virtually no harmful affects to the environment. /Filter /LZWDecode
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HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: CAUTION! 2. 8" x 12" Recommended for large pails, tubs, and drums. Return to HazMat Table menu at top of page. ���Ѩ�l.��q��\9� 8" x 12" Recommended for large pails, tubs, and drums. Dry, or anhydrous, calcium chloride is referred to by Hill Brothers’ trade name as Hi 94.Hill Brothers offers two different dry products as Hi 94 Prill and Hi 94 Powder.Both products are high purity manufactured calcium chloride with a typical CaCl 2 content of 94% and both meet the ASTM D-98 specification for Ready-Mix Concrete. $59.98 $ 59. %����
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Danger Calcium Chloride Sign - S-8188 - from MySafetySign.com. ���Cm�}i>EBx;trJ���p��a=t���4>b��Ja@���xx �E�@X@oz�Ѫ�p�C�a{`��Pd`P2|k��F�כ��ϴ��~�`� MI10432 Revision date 01/Apr/2014 4. May cause cardiac disturbances. /Length 9 0 R
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Calcium chloride, because of its acidifying nature, is unsuitable for the treatment of hypocalcaemia caused by renal insufficiency or in patients with respiratory acidosis or failure. May be harmful if swallowed. endobj
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Poor stability of the emulsion results in the two … Tell your doctor about the allergy and what signs you had. Calcium chloride has a variety of applications and can lead to potential health risks if handled improperly. ��"sh!��h�2��* "4�� "x� .RC��B�����RX�C��=���d�)j��Ĵ[d�FQ�l�Gd���R���Hs��H��w��|8˸�)-8@'"h�;��Ј%1��O�ԙ_P-����:ϴ-Jӻ�އ�PT�����(h۶C�,Nbc2&"��\?�թ^��L�>5PeH�7�C�4���6��]h����Ԃ2}S=S��( ���;]uͧ^!�;i`B��p��j^'�*��2����9e�`�7#c0�:�# @0�� �:
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: OSHA Hazard Communication Compliance Guide - see Section 3 Ensure Containers are Labeled. Wash thoroughly after handling. In its liquid form, it contains from 30% to 42% of calcium chloride per liter of solution, usually sold as 30% solution. Water (CAS-No.) The U.S. Department of Transportation's hazardous materials placard guidelines are aligned with international, interstate and local standards. This can cause clumping and caking in dry calcium chloride products, such as pellets, flakes and briquettes. Ramachandran. stream
Calcium chloride is deliquescent. Precipitations of ceftriaxone-calcium salt, including fatalities, have been seen in newborns under 28 days old, both pre-term and full term, treated with intravenous ceftriaxone and calcium. 't#1s̫�BN��5�`���Z�FQ���Y&�6��Q=��4W�po���v@�x9JT�%9lr�y^��B���Ў���0��d8s���k(��ǣ���B�P�+Eo��t��;�d��%:MJ)U,Vj�;����s��O���c���-����phwj��O����|� x6 Avoid breathing airborne product. Calcium carbide incandesces with chlorine, bromine, or iodine at 245, 350, or 305°C., respectively, [Mellor, 1946, Vol. Use with adequate ventilation. Calcium chloride attracts moisture from the air, keeping the road damp even under hot, dry conditions. Calcium Chloride CaCl. It is proposed that aluminum chloride works by causing an obstruction of the distal sweat gland ducts, where the metal ions precipitate with mucopolysaccharides, damaging epithelial cells along the lumen of the duct and forming a plug that blocks sweat output [A32368]. ���
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If benzalkonium chloride soaks or calcium gluconate gel do not provide significant relief of pain within 30 to 40 minutes, injection of calcium gluconate solution is indicated. Calcium Chloride for Plants. Long term exposure of calcium chloride solution upon a zinc coated galvanized iron vessel caused slow evolution of hydrogen which ignited and exploded [Bretherick, 5th Ed., 1995]. 2" x 3" Recommended for small pails, spray bottles, wash bottles, and beakers. Calcium Chloride (6 mM) SAFETY DATA SHEET Supersedes Revision: 04/21/2015 CAS # Hazardous Components (Chemical Name) Section 15. First Aid Measures Summary of First Aid Measures Ingestion : Do not induce vomiting. Sigma-Aldrich offers a number of Calcium chloride products. Durable laminate that increases the label strength and resistance. /Parent 5 0 R
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